Application of silicon nanowires and indium tin oxide surfaces in desorption electrospray ionization.
Identifieur interne : 002449 ( Main/Exploration ); précédent : 002448; suivant : 002450Application of silicon nanowires and indium tin oxide surfaces in desorption electrospray ionization.
Auteurs : RBID : pubmed:19136727English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Cyclosporine, Silicon, Tin Compounds.
- methods : Spectrometry, Mass, Electrospray Ionization.
- Nanostructures, Nanowires, Reproducibility of Results, Surface Properties, Uncertainty.
Abstract
Two nanostructured surfaces are introduced as advantageous substrates for desorption electrospray ionization mass spectrometry (DESI-MS). Nano-assisted laser desorption/ionization (NALDI) plates coated with silicon nanowires (SiNWs) and indium tin oxide (ITO) layers on glass are both conductive non-polar surfaces that were originally designed as superior substrates for matrix-free laser desorption/ionization. In this study, NALDI/SiNWs and ITO were tested as potentially useful DESI substrates for selected model analytes (cyclosporine, beauverolide, surfactin and nystatin). Both nanostructured surfaces produced more intense and longer-lasting signals than other tested surfaces (polytetrafluoroethylene, glass, polymethylmethacrylate and chromatography paper).
DOI: 10.1255/ejms.961
PubMed: 19136727
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Le document en format XML
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<author><name sortKey="P L, Jaroslav" uniqKey="P L J">Jaroslav Pól</name>
<affiliation><nlm:affiliation>Laboratory of Molecular Structure Characterization, Institute of Microbiology, Academy of Sciences of the Czech Republic. jaroslav.pol@helsinki.fi</nlm:affiliation>
<country wicri:rule="url">Finlande</country>
</affiliation>
</author>
<author><name sortKey="Nov K, Petr" uniqKey="Nov K P">Petr Novák</name>
</author>
<author><name sortKey="Voln, Michael" uniqKey="Voln M">Michael Volný</name>
</author>
<author><name sortKey="Kruppa, Gary H" uniqKey="Kruppa G">Gary H Kruppa</name>
</author>
<author><name sortKey="Kostiainen, Risto" uniqKey="Kostiainen R">Risto Kostiainen</name>
</author>
<author><name sortKey="Lemr, Karel" uniqKey="Lemr K">Karel Lemr</name>
</author>
<author><name sortKey="Havl Cek, Vladim R" uniqKey="Havl Cek V">Vladimír Havlícek</name>
</author>
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<publicationStmt><date when="2008">2008</date>
<idno type="doi">10.1255/ejms.961</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cyclosporine (chemistry)</term>
<term>Nanostructures</term>
<term>Nanowires</term>
<term>Reproducibility of Results</term>
<term>Silicon (chemistry)</term>
<term>Spectrometry, Mass, Electrospray Ionization (methods)</term>
<term>Surface Properties</term>
<term>Tin Compounds (chemistry)</term>
<term>Uncertainty</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Cyclosporine</term>
<term>Silicon</term>
<term>Tin Compounds</term>
</keywords>
<keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Spectrometry, Mass, Electrospray Ionization</term>
</keywords>
<keywords scheme="MESH" xml:lang="en"><term>Nanostructures</term>
<term>Nanowires</term>
<term>Reproducibility of Results</term>
<term>Surface Properties</term>
<term>Uncertainty</term>
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<front><div type="abstract" xml:lang="en">Two nanostructured surfaces are introduced as advantageous substrates for desorption electrospray ionization mass spectrometry (DESI-MS). Nano-assisted laser desorption/ionization (NALDI) plates coated with silicon nanowires (SiNWs) and indium tin oxide (ITO) layers on glass are both conductive non-polar surfaces that were originally designed as superior substrates for matrix-free laser desorption/ionization. In this study, NALDI/SiNWs and ITO were tested as potentially useful DESI substrates for selected model analytes (cyclosporine, beauverolide, surfactin and nystatin). Both nanostructured surfaces produced more intense and longer-lasting signals than other tested surfaces (polytetrafluoroethylene, glass, polymethylmethacrylate and chromatography paper).</div>
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<Day>12</Day>
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<DateCompleted><Year>2009</Year>
<Month>03</Month>
<Day>23</Day>
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<DateRevised><Year>2013</Year>
<Month>11</Month>
<Day>21</Day>
</DateRevised>
<Article PubModel="Print"><Journal><ISSN IssnType="Print">1469-0667</ISSN>
<JournalIssue CitedMedium="Print"><Volume>14</Volume>
<Issue>6</Issue>
<PubDate><Year>2008</Year>
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<Title>European journal of mass spectrometry (Chichester, England)</Title>
<ISOAbbreviation>Eur J Mass Spectrom (Chichester, Eng)</ISOAbbreviation>
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<ArticleTitle>Application of silicon nanowires and indium tin oxide surfaces in desorption electrospray ionization.</ArticleTitle>
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<Abstract><AbstractText>Two nanostructured surfaces are introduced as advantageous substrates for desorption electrospray ionization mass spectrometry (DESI-MS). Nano-assisted laser desorption/ionization (NALDI) plates coated with silicon nanowires (SiNWs) and indium tin oxide (ITO) layers on glass are both conductive non-polar surfaces that were originally designed as superior substrates for matrix-free laser desorption/ionization. In this study, NALDI/SiNWs and ITO were tested as potentially useful DESI substrates for selected model analytes (cyclosporine, beauverolide, surfactin and nystatin). Both nanostructured surfaces produced more intense and longer-lasting signals than other tested surfaces (polytetrafluoroethylene, glass, polymethylmethacrylate and chromatography paper).</AbstractText>
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<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Pól</LastName>
<ForeName>Jaroslav</ForeName>
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<Affiliation>Laboratory of Molecular Structure Characterization, Institute of Microbiology, Academy of Sciences of the Czech Republic. jaroslav.pol@helsinki.fi</Affiliation>
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<ChemicalList><Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance>Tin Compounds</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>71243-84-0</RegistryNumber>
<NameOfSubstance>indium tin oxide</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>83HN0GTJ6D</RegistryNumber>
<NameOfSubstance>Cyclosporine</NameOfSubstance>
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<Chemical><RegistryNumber>Z4152N8IUI</RegistryNumber>
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<MeshHeading><DescriptorName MajorTopicYN="N">Spectrometry, Mass, Electrospray Ionization</DescriptorName>
<QualifierName MajorTopicYN="Y">methods</QualifierName>
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<MeshHeading><DescriptorName MajorTopicYN="Y">Surface Properties</DescriptorName>
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<MeshHeading><DescriptorName MajorTopicYN="N">Tin Compounds</DescriptorName>
<QualifierName MajorTopicYN="Y">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N">Uncertainty</DescriptorName>
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